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Gypsum hydration: a theoretical and experimental study Calcium sulphate dihydrate (CaSO4·2H2O or gypsum) is used widely as building material because of its excellent fire resistance, aesthetics, and low price. Hemihydrate occurs in two formations of α and βtype. Among them βhemihydrate .

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A pilot scale preparation of αcalcium sulfate hemihydrate (αHH) from flue gas desulfurization (FGD) gypsum was conducted for the first time in mixed salt solutions under atmospheric pressure.

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After the first reaction in hemihydrate mode, the resulting acid is separated. It has a low sulfate content and contains 46% P 2 O it has been washed, the remaining alpha hemihydrate is mixed with the sulfuric acid, under conditions in which the alpha hemihydrate is unstable and recrystallized like gypsum, producing a cocrystallized and unattacked gypsum with a low P 2 O 5 content.

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